nss-gui: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On CentOS possible default full paths are:

/usr/bin/nss-gui - from package: nss-gui

You may install the required package with command yum install {package}
Error in other languages:
nss-gui: bevel nie gevind nie
nss-gui: comandă negăsită
nss-gui: comando não encontrado
nss-gui: commande introuvable
nss-gui: command not found
nss-gui: käsku ei ole
nss-gui: không tìm thấy lệnh
nss-gui: komanda nerasta
nss-gui: Kommando nicht gefunden.
nss-gui: kommandot finns inte
nss-gui: komut yok
nss-gui: nie znaleziono polecenia
nss-gui: níor aimsíodh an t-ordú
nss-gui: no se encontró la orden
nss-gui: no s'ha trobat l'ordre
nss-gui: opdracht niet gevonden
nss-gui: parancs nem található
nss-gui: perintah tidak ditemukan
nss-gui: príkaz nenájdený
nss-gui: příkaz nenalezen
nss-gui: команда не найдена
nss-gui: командата не е открита
nss-gui: 命令找不到
nss-gui: コマンドが見つかりません