mpdman.py: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On CentOS possible default full paths are:

/usr/bin/mpdman.py - from package: mpich2

You may install the required package with command yum install {package}
Error in other languages:
mpdman.py: bevel nie gevind nie
mpdman.py: comandă negăsită
mpdman.py: comando não encontrado
mpdman.py: commande introuvable
mpdman.py: command not found
mpdman.py: käsku ei ole
mpdman.py: không tìm thấy lệnh
mpdman.py: komanda nerasta
mpdman.py: Kommando nicht gefunden.
mpdman.py: kommandot finns inte
mpdman.py: komut yok
mpdman.py: nie znaleziono polecenia
mpdman.py: níor aimsíodh an t-ordú
mpdman.py: no se encontró la orden
mpdman.py: no s'ha trobat l'ordre
mpdman.py: opdracht niet gevonden
mpdman.py: parancs nem található
mpdman.py: perintah tidak ditemukan
mpdman.py: príkaz nenájdený
mpdman.py: příkaz nenalezen
mpdman.py: команда не найдена
mpdman.py: командата не е открита
mpdman.py: 命令找不到
mpdman.py: コマンドが見つかりません