mpdexit.py: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On CentOS possible default full paths are:

/usr/bin/mpdexit.py - from package: mpich2

You may install the required package with command yum install {package}
Error in other languages:
mpdexit.py: bevel nie gevind nie
mpdexit.py: comandă negăsită
mpdexit.py: comando não encontrado
mpdexit.py: commande introuvable
mpdexit.py: command not found
mpdexit.py: käsku ei ole
mpdexit.py: không tìm thấy lệnh
mpdexit.py: komanda nerasta
mpdexit.py: Kommando nicht gefunden.
mpdexit.py: kommandot finns inte
mpdexit.py: komut yok
mpdexit.py: nie znaleziono polecenia
mpdexit.py: níor aimsíodh an t-ordú
mpdexit.py: no se encontró la orden
mpdexit.py: no s'ha trobat l'ordre
mpdexit.py: opdracht niet gevonden
mpdexit.py: parancs nem található
mpdexit.py: perintah tidak ditemukan
mpdexit.py: príkaz nenájdený
mpdexit.py: příkaz nenalezen
mpdexit.py: команда не найдена
mpdexit.py: командата не е открита
mpdexit.py: 命令找不到
mpdexit.py: コマンドが見つかりません