mkvinfo: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On CentOS possible default full paths are:

/usr/bin/mkvinfo - from package: mkvtoolnix-gui

You may install the required package with command yum install {package}
Error in other languages:
mkvinfo: bevel nie gevind nie
mkvinfo: comandă negăsită
mkvinfo: comando não encontrado
mkvinfo: commande introuvable
mkvinfo: command not found
mkvinfo: käsku ei ole
mkvinfo: không tìm thấy lệnh
mkvinfo: komanda nerasta
mkvinfo: Kommando nicht gefunden.
mkvinfo: kommandot finns inte
mkvinfo: komut yok
mkvinfo: nie znaleziono polecenia
mkvinfo: níor aimsíodh an t-ordú
mkvinfo: no se encontró la orden
mkvinfo: no s'ha trobat l'ordre
mkvinfo: opdracht niet gevonden
mkvinfo: parancs nem található
mkvinfo: perintah tidak ditemukan
mkvinfo: príkaz nenájdený
mkvinfo: příkaz nenalezen
mkvinfo: команда не найдена
mkvinfo: командата не е открита
mkvinfo: 命令找不到
mkvinfo: コマンドが見つかりません