kioexec: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On CentOS possible default full paths are:

/usr/bin/kioexec - from package: kdelibs3

You may install the required package with command yum install {package}
Error in other languages:
kioexec: bevel nie gevind nie
kioexec: comandă negăsită
kioexec: comando não encontrado
kioexec: commande introuvable
kioexec: command not found
kioexec: käsku ei ole
kioexec: không tìm thấy lệnh
kioexec: komanda nerasta
kioexec: Kommando nicht gefunden.
kioexec: kommandot finns inte
kioexec: komut yok
kioexec: nie znaleziono polecenia
kioexec: níor aimsíodh an t-ordú
kioexec: no se encontró la orden
kioexec: no s'ha trobat l'ordre
kioexec: opdracht niet gevonden
kioexec: parancs nem található
kioexec: perintah tidak ditemukan
kioexec: príkaz nenájdený
kioexec: příkaz nenalezen
kioexec: команда не найдена
kioexec: командата не е открита
kioexec: 命令找不到
kioexec: コマンドが見つかりません