kdeinit_shutdown: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On CentOS possible default full paths are:

/usr/bin/kdeinit_shutdown - from package: kdelibs3

You may install the required package with command yum install {package}
Error in other languages:
kdeinit_shutdown: bevel nie gevind nie
kdeinit_shutdown: comandă negăsită
kdeinit_shutdown: comando não encontrado
kdeinit_shutdown: commande introuvable
kdeinit_shutdown: command not found
kdeinit_shutdown: käsku ei ole
kdeinit_shutdown: không tìm thấy lệnh
kdeinit_shutdown: komanda nerasta
kdeinit_shutdown: Kommando nicht gefunden.
kdeinit_shutdown: kommandot finns inte
kdeinit_shutdown: komut yok
kdeinit_shutdown: nie znaleziono polecenia
kdeinit_shutdown: níor aimsíodh an t-ordú
kdeinit_shutdown: no se encontró la orden
kdeinit_shutdown: no s'ha trobat l'ordre
kdeinit_shutdown: opdracht niet gevonden
kdeinit_shutdown: parancs nem található
kdeinit_shutdown: perintah tidak ditemukan
kdeinit_shutdown: príkaz nenájdený
kdeinit_shutdown: příkaz nenalezen
kdeinit_shutdown: команда не найдена
kdeinit_shutdown: командата не е открита
kdeinit_shutdown: 命令找不到
kdeinit_shutdown: コマンドが見つかりません