iotk_openmpi: command not found

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On CentOS possible default full paths are:

/usr/lib64/openmpi/bin/iotk_openmpi - from package: quantum-espresso-openmpi

You may install the required package with command yum install {package}

Error in other languages:
iotk_openmpi: bevel nie gevind nie
iotk_openmpi: comandă negăsită
iotk_openmpi: comando não encontrado
iotk_openmpi: commande introuvable
iotk_openmpi: command not found
iotk_openmpi: käsku ei ole
iotk_openmpi: không tìm thấy lệnh
iotk_openmpi: komanda nerasta
iotk_openmpi: Kommando nicht gefunden.
iotk_openmpi: kommandot finns inte
iotk_openmpi: komut yok
iotk_openmpi: nie znaleziono polecenia
iotk_openmpi: níor aimsíodh an t-ordú
iotk_openmpi: no se encontró la orden
iotk_openmpi: no s'ha trobat l'ordre
iotk_openmpi: opdracht niet gevonden
iotk_openmpi: parancs nem található
iotk_openmpi: perintah tidak ditemukan
iotk_openmpi: príkaz nenájdený
iotk_openmpi: příkaz nenalezen
iotk_openmpi: команда не найдена
iotk_openmpi: командата не е открита
iotk_openmpi: 命令找不到
iotk_openmpi: コマンドが見つかりません