gpmetis64: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On CentOS possible default full paths are:

/usr/bin/gpmetis64 - from package: metis64

You may install the required package with command yum install {package}
Error in other languages:
gpmetis64: bevel nie gevind nie
gpmetis64: comandă negăsită
gpmetis64: comando não encontrado
gpmetis64: commande introuvable
gpmetis64: command not found
gpmetis64: käsku ei ole
gpmetis64: không tìm thấy lệnh
gpmetis64: komanda nerasta
gpmetis64: Kommando nicht gefunden.
gpmetis64: kommandot finns inte
gpmetis64: komut yok
gpmetis64: nie znaleziono polecenia
gpmetis64: níor aimsíodh an t-ordú
gpmetis64: no se encontró la orden
gpmetis64: no s'ha trobat l'ordre
gpmetis64: opdracht niet gevonden
gpmetis64: parancs nem található
gpmetis64: perintah tidak ditemukan
gpmetis64: príkaz nenájdený
gpmetis64: příkaz nenalezen
gpmetis64: команда не найдена
gpmetis64: командата не е открита
gpmetis64: 命令找不到
gpmetis64: コマンドが見つかりません