config.PLS: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On Debian possible default full paths are:

/usr/share/gmod/chado/bin/config.PLS - from package: libchado-perl

You may install the required package with command apt-get install {package}
Error in other languages:
config.PLS: bevel nie gevind nie
config.PLS: comandă negăsită
config.PLS: comando não encontrado
config.PLS: commande introuvable
config.PLS: command not found
config.PLS: käsku ei ole
config.PLS: không tìm thấy lệnh
config.PLS: komanda nerasta
config.PLS: Kommando nicht gefunden.
config.PLS: kommandot finns inte
config.PLS: komut yok
config.PLS: nie znaleziono polecenia
config.PLS: níor aimsíodh an t-ordú
config.PLS: no se encontró la orden
config.PLS: no s'ha trobat l'ordre
config.PLS: opdracht niet gevonden
config.PLS: parancs nem található
config.PLS: perintah tidak ditemukan
config.PLS: príkaz nenájdený
config.PLS: příkaz nenalezen
config.PLS: команда не найдена
config.PLS: командата не е открита
config.PLS: 命令找不到
config.PLS: コマンドが見つかりません