amsn-remote-CLI: command not found

Have You tried accessing the binary with the full path?

Maybe Your $PATH variable doesn't contain the default paths? echo $PATH should give something like:

[root@server ~]# echo $PATH
/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin

If it's empty, You may set the PATH variable with this command

export PATH="/usr/local/sbin:/usr/local/bin:/sbin:/bin:/usr/sbin:/usr/bin:/root/bin"

On Debian possible default full paths are:

/usr/bin/amsn-remote-CLI - from package: amsn

You may install the required package with command apt-get install {package}
Error in other languages:
amsn-remote-CLI: bevel nie gevind nie
amsn-remote-CLI: comandă negăsită
amsn-remote-CLI: comando não encontrado
amsn-remote-CLI: commande introuvable
amsn-remote-CLI: command not found
amsn-remote-CLI: käsku ei ole
amsn-remote-CLI: không tìm thấy lệnh
amsn-remote-CLI: komanda nerasta
amsn-remote-CLI: Kommando nicht gefunden.
amsn-remote-CLI: kommandot finns inte
amsn-remote-CLI: komut yok
amsn-remote-CLI: nie znaleziono polecenia
amsn-remote-CLI: níor aimsíodh an t-ordú
amsn-remote-CLI: no se encontró la orden
amsn-remote-CLI: no s'ha trobat l'ordre
amsn-remote-CLI: opdracht niet gevonden
amsn-remote-CLI: parancs nem található
amsn-remote-CLI: perintah tidak ditemukan
amsn-remote-CLI: príkaz nenájdený
amsn-remote-CLI: příkaz nenalezen
amsn-remote-CLI: команда не найдена
amsn-remote-CLI: командата не е открита
amsn-remote-CLI: 命令找不到
amsn-remote-CLI: コマンドが見つかりません